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Also, the validity of the model was verified by corresponding experiments. Hence, the model can be applied to other PVDF ternary membrane systems by modifying specific thermodynamic and kinetic parameters.Developing waterborne epoxy (WEP) coatings with excellent corrosion resistance and tribological properties is a key aspect to solve the damage of Q235 steel. In this work, perylene bisimide (PBI) derivatives dispersion graphene (GR) were prepared by a π-π stacking, the highly orientated PBI0.5%/GR0.5%/WEP coating will be prepared by the rotating coating method. Especially, the impedance value reached about 109 Ω·cm2 when the PBI and GR ratio is 11. The impedance value of PBI0.5%/GR0.5%/WEP coating increased by 3 orders of magnitude compared with that of pure WEP coating (106 Ω·cm2). Additionally, the coefficient of friction of the coatings was 0.33; compared with that of WEP, the coefficient of friction decreased by 48%, and the wear resistance increased by 87.6%. The results show that the PBI0.5%/GR0.5%/WEP coatings exhibited excellent corrosion resistance and wear resistance properties due to the good dispersion and high orientation of PBI/GR in WEP. It is anticipated that our current work would guide the ongoing efforts to develop a more efficient method to overcome the poor dispersion of GR in waterborne epoxy resin and provide a green coating with excellent corrosion resistance and wear resistance properties.Aging is associated with loss of muscle mass and strength that leads to a condition termed sarcopenia. Impaired conditions, morbidity, and malnutrition are the factors of devaluation of muscle fibers in aged animals. https://www.selleckchem.com/products/gsk805.html Satellite cells play an important role in maintaining muscle homeostasis during tissue regeneration and repair. Proteomic profiling on the skeletal muscle tissues of different age group rats helps to determine the differentially expressed (DE) proteins, which may eventually lead to the development of biomarkers in treating the conditions of sarcopenia. In this study, nanoscale liquid chromatography coupled to tandem mass spectrometry (nano-LC-MS/MS) analysis was implemented in the calf tissues of young and old groups of rats. The mass spectrometry (MS) analysis revealed the presence of 335 differentially expressed proteins between the two different age conditions, among which those based on log-fold change 25 proteins were upregulated and 77 were downregulated. The protein-protein interaction network analysis revealed 18 upregulated proteins with three distinct interconnected networks and 57 downregulated proteins with two networks. Further, gene ontology (GO) enrichment analysis showed the biological process, cellular component, and molecular function of the differential proteins. Pathway enrichment analysis of the DE proteins identified nine significantly enriched pathways with a list of eight significant genes (Cryab, Hspb2, Acat1, Ak1, Adssl1, Anxa5, Gys1, Ogdh, Gc, and Adssl1). Quantification of significant genes by quantitative real-time polymerase chain reaction (qRT-PCR) confirmed the downregulation at the mRNA level. Western blot analysis of their protein expression showed concordant results on two candidate proteins (Ogdh and annexin 5) confirming their differential regulation between the two age groups of rats. Thus, these proteomic approaches on young and aged rats provide insights into the development of protein targets in the treatment of sarcopenia (muscle loss).In this study, we prepared a polypyrrole-diphenyl diselenide [PPy/(PhSe)2] nanocomposite by oxidative chemical polymerization for the purpose of temperature sensing applications. Fourier transform infrared spectroscopy, X-ray diffraction and scanning transmission electron microscopy confirmed the synthesis of the above material. Thermogravimetry (TG) revealed enhanced thermal stability as compared to pristine polypyrrole (PPy). Dielectric study showed the material to have a dielectric constant of colossal value. The material has been found to exhibit correlated barrier hopping conduction (CBH) wherein hopping of charge carriers takes place over the insulating (PhSe)2 barrier. The maximum barrier height was found to be 0.224 eV. The nanocomposite material was found to exhibit a switching-type positive temperature coefficient (PTC) behavior with a Curie temperature of 400 K. This has been explained by a CBH model wherein PPy chains expand upon heating, thereby reducing the barrier height to facilitate current flow. However, above 400 K, disruption of PPy chains allows to reflect a PTC behavior. This has been in agreement with TG data.Zn-Al layered bimetallic composites were prepared by ethanol strengthening and co-precipitation using banana straw as a raw material. A high-efficiency phosphorus adsorbent (ZnAl-LDO-BC) was obtained by calcination at a high temperature. The kinetics and thermodynamics of phosphorus adsorption on ZnAl-LDO-BC were then studied. The results showed that the adsorption process of ZnAl-LDO-BC corresponds with the pseudo-second-order (PSO) kinetic equation and the Langmuir model. The theoretical maximum adsorption capacity of ZnAl-LDO-BC is 111.11 mg/g (at 45 °C, 500 mg/L phosphorus initial concentration). The influence of anions on phosphorus adsorption decreased in strength in the following order CO3 2- > SO4 2- > NO3 -. Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) were used to characterize the adsorption of phosphorus on ZnAl-LDO-BC and showed that ZnAl-LDO-BC can efficiently adsorb phosphorus. The adsorption mechanism utilizes both O-H and C-H on the surface of ZnAl-LDO-BC for the adsorption of PO4 3-, forming Zn3(PO4)2·4H2O via complexation precipitation; additionally, biochar surface adsorption and interlayer adsorption are indispensable forms of phosphate adsorption. With the systematic study of phosphorus adsorption by ZnAl-LDO-BC, a novel green technology was developed for addressing phosphorus pollution.Measurement of cooking-associated air pollution indoors is an integral part of exposure monitoring and human health risk assessment. There is a need for easy to use, fast, and economical detection systems to quantify the various emissions from different sources in the home. Addressing this challenge, a colorimetric sensor array (CSA) is reported as a new method to characterize volatile organic compounds produced from cooking, a major contributor to indoor air pollution. The sensor array is composed of pH indicators and aniline dyes from classical spot tests, which enabled molecular recognition of a variety of aldehydes, ketones, and carboxylic acids as demonstrated by hierarchical clustering and principal component analyses. To demonstrate the concept, these CSAs were employed for differentiation of emissions from heated cooking oils (sunflower, rapeseed, olive, and groundnut oils). Sensor results were validated by gas chromatography-mass spectrometry analysis, highlighting the potential of the sensor array for evaluating cooking emissions as a source of indoor air pollution.https://www.selleckchem.com/products/gsk805.html