Run inxi -Naz
to make sure your USB Wi-Fi is recognize by the OS
Choosing right Wi-Fi device is confusing for some desktop envionment
Here, in KDE Plasma there is no way to distinguish my desired SSID will connect through which one as I have two Wi-Fi receiver in my device (One is Built-In PCI another one is USB dongle picture showed above)
nmtui
could be your lifesaver.
If you run nmtui-connect
from terminal you can see list of available Wi-Fi device to connect separately for PCB and USB. Which was not the case for KDE GUI
Hope this guide will help someone
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