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This was attributed to the lower density of the air and the higher dissipation of turbulent kinetic energy due to bubble-liquid interactions in the two-phase flow case.Knowledge of particulate system properties is very important in various industrial instances and the possibility of fast predicting the behavior of such systems is an important control tool. https://www.selleckchem.com/products/k-ras-g12c-inhibitor-12.html The specific surface area of simulated particulate systems was studied as a function of the sharpness parameter of the size distribution of the Gates-Gaudin-Schumann, Gaudin-Meloy and Rosin-Rammler equations. The results showed good statistical adherence, especially the Rosin-Rammler equation, in situations where it is the best descriptor of particle size distribution.We investigated the changes in the physical structure of cellulose recovered from soybean and rice hulls treated with the ionic liquids 1-butyl-3-methylimidazolium chloride ([bmim][Cl]) and 1-butyl-3-methylimidazolium acetate ([bmim][Ac]). The characterization was carried out by a combination of thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Regenerated cellulose from soybean hull showed loss of crystallinity and high structural disruption caused by both ionic liquid treatments as compared to the untreated material. In contrast, rice hull presented only a small structural disruption when treated with [bmim][Ac] and was practically unaffected by [bmim][Cl], showing that this biomass residue is recalcitrance towards physico-chemical treatments, possibly as a consequence of its high composition content in silica. These results suggest the use of soybean hull as a substrate to be treated with ionic liquids in the preparation of lignocellulosic hydrolysates to be used in second-generation ethanol production, whereas other methods should be considered to treat rice hull biomass.The aim of this work was to investigate the phenolic content and antioxidant capacity of infusions of commercial herb samples (fennel, anise, peppermint, lemon grass and lemon balm) popularly consumed in Brazil. The infusion preparation for phenolic extraction was optimized using multivariate planning. Spectrophotometric methods were used to determine in vitro antioxidant activity and total phenolic and flavonoid content. Peppermint infusions had higher phenolic content and antioxidant potential. It was developed and validated a method by HPLC-DAD for the determination of caffeine, phenolic acids and flavonoids and applied for the analysis of the composition of the infusions. Higher concentrations were obtained for chlorogenic and p-coumaric phenolic acids and for flavonoids rutin and catechin. Principal Components Analysis and Hierarchical Cluster Analysis were applied for the comparative evaluation of the phenolic composition of the infusions. The multivariate analyzes indicate that the phenolic profile for the samples of the same species tend to present greater similarities in relation to other herbs and one of the analyzed samples, commercialized as anise, does not belong to the P. anisum species.Taste and odor compounds affect drinking water safety perception and may drive consumers to less secure water sources. Adsorption, using powered activated carbon, is the most common method to remove these compounds but greatly increases the amount of sludge generated. Another way of removing taste and odor compounds is to use filters with granular activated carbon (GAC) but little is still known on how to design them. In this work, the homogeneous surface diffusion model (HSDM) was used to model bench-scale kinetic and isotherm experiments and to simulate the removal of geosmin in a full-scale GAC filter. Geosmin adsorption isotherm was best described by the Freundlich model in all used carbons and film resistance (Kf) was more relevant to adsorption kinetics than pore diffusion (Ds). The simulation showed that in a filter with an empty bed contact time of 5 minutes and raw water with geosmin concentrations of 50, 75, and 100 ng.L-1, the effluent would exceed the trash-hold concentration (10 ng.L-1) in 98, 77, and 66 days, respectively, without considering biological removal.Activated biochars were prepared from residues of medium density fiberboard (MDF) produced by the furniture industry. Biomass residue was pre-treated with FeCl3 in two different FeCl3biomass ratios (0.51 and 11, w/w) aiming to produce a matrix embedded with iron oxide. The pyrolysis process produced maghemite on the biochar surface and its magnetic properties were confirmed by its attraction to a hand magnet and its magnetic susceptibility. Samples were also characterized using scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), surface area by BET-N2, Fourier transform infrared (FTIR), X-ray diffraction, magnetic susceptibility, and cation exchange capacity (CEC). Magnetic biochar exhibited up to twelve-fold higher surface area than the non-magnetic biochar, which varies according the maghemite particles content. Iron oxide on biochar surface also contributed for increasing CEC around ten-fold compared to non-magnetic biochars. Phosphorus adsorption isotherms showed that these magnetic biochars have high capacity to sorb oxyanions like phosphate, especially at lower pH. Thus, these magnetic biochars could be used to clean water bodies contaminated with oxyanions in acidic conditions.Plant responses to nitrogen supply are dependent on auxin signaling, but much still remains to be elucidated regarding N deficiency in tomato. Thus, the objective of this work was to evaluate how low auxin sensitivity regulates the responses of tomato plants to N deficiency. For this purpose, we used the tomato diageotropica mutant, with low auxin sensitivity, and a near isogenic line cv. Micro-Tom grown in nutrient solutions under absence and presence of nitrogen. Plant height, stem diameter, root and shoot dry mass, area and root density, number of lateral roots, leaf area, chlorophylls and carotenoids content, nitrogen accumulation and nitrogen use efficiency were evaluated. We observed a clear interaction between the tomato genotype and nitrogen. When the plants were grown with nitrogen, 'Micro-Tom' showed higher growth than the diageotropica mutant. Under nitrogen deficiency condition, the mutant showed improved growth, nitrogen use efficiency and higher contents of pigments. In general, the low sensitivity to auxin in diageotropica caused reduced growth in both shoot and root.https://www.selleckchem.com/products/k-ras-g12c-inhibitor-12.html